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Zamojski's Total Synthesis of Racemic Monosaccharides as an Inspiration for Stereoselective Transformations of Readily Available Sugar Synthons
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pp.973-984 (12) Authors: Marek Chmielewski, Sebastian Stecko, Wioletta Kosnik
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| Abstract |
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The present account reports on the E-α,β-unsaturated-δ-butoxycarbonyl-δ-hydroxy-aldehyde (3), acetal hydroperoxide (4) and α,β-unsaturated-δ-lactone (5), obtained during Zamojski's total synthesis of carbohydrates. Properties of these and related compounds, and their further applications in organic synthesis are discussed.
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Keywords:
Zamojski's Total Synthesis, Racemic Monosaccharides, Stereoselective Transformations, Sugar Synthons, carbohydrates, organic synthesis, Anomeric Hydroperoxides
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Affiliation:
Institute of Organic Chemistry of the Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland.
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