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Current Organic Synthesis

Volume 5 Issue 3
ISSN: 1570-1794
eISSN: 1875-6271

 

   All Titles

  Asymmetric Epoxidation of Electron-Deficient Olefins
  pp.186-216 (31) Authors: David Diez, Marta G. Nunez, Ana B. Anton, P. Garcia, R. .F. Moro, N. M. Garrido, Isidro S. Marcos, P. Basabe, Julio G. Urones
 
 
      Abstract

This paper focuses on the latest developments in asymmetric epoxidation of electron-deficient olefins since the review by Porter and Skidmore on chiral ligand-metal peroxide systems, polyamino acid catalysed and organocatalysed epoxidations. Particular attention has been paid to the most recent advances using chiral pyrrolidines as organocatalysts.

 
  Keywords: Asymmetric epoxidation, electron deficient olefins, organocatalysis, dioxiranes, chiral ligand, –, metal peroxide systems, Juliá Colonna epoxidation
  Affiliation: Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad de Salamanca, 37006 Salamanca, Spain.
 
  Key: New Content Free Content Open Access Plus Subscribed Content

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